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Circularly polarized luminescent(CPL)materials with intense emission and high luminescence dissymmetry factor(glum)are highly de-sirable for their promising applications in communication technologies,nanotechnologies,innovative materials,etc.Motivated by benefits in supramolecular chemistry and aggregation-induced emission(AlE)materials for the development of advanced lumines-cent materials,herein,we report a new class of CPL-active AlE luminogens(AIEgens)by incorporating the p-terphenylene(TP)with chiral alkoxyl chains.