Effects of precursor solution concentration on the properties and morphology of YBCO films deposited

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Epitaxial YBCO films were deposited on (100) LaAlO3 single-crystal substrates by metalorganic deposition ofmetal trifluoroacetate precursors with different concentrations. All the YBCO films have Tc around 91 K and Jc excess 2MA/cm2 at 77 K in zero field. XRD θ-2θscans show all the films have c-axis normal orientation. The FWHM (full width athalf-maximum intensity) values of X-ray ω-scans of (005) reflection are 0.379°, 0.283°, and 0.543° for the YBCO thin filmsdeposited with precursor solution concentrations of 1.52, 1.0, and 0.75 mol/L, respectively. With the concentration of theprecursors decreasing, the thickness of the films decreases linearly. SEM micrographs show that porosities in the films be-come bigger with the precursor solution concentration decreasing. The big porosities in the film with the lowest concentra-tion precursor deteriorate the superconducting property and make it have a wider superconducting transition and a lower Jc. Epitaxial YBCO films were deposited on (100) LaAlO3 single-crystal substrates by metalorganic deposition ofmetal trifluoroacetate precursors with different concentrations. All the YBCO films have Tc around 91 K and Jc excess 2MA / cm2 at 77 K in zero field. XRD θ-2θscans The FWHM (full width athalf-maximum intensity) values ​​of X-ray ω-scans of (005) reflection are 0.379 °, 0.283 °, and 0.543 ° for the YBCO thin films deposited with With the concentration of theprecursors decreasing, the thickness of the films decreases linearly. SEM micrographs show that porosities in the films be-come bigger with the precursor solution concentration decreasing. The big porosities in the film with the lowest concentra-tion precursor deter rate the superconducting property and make it have a wider superconducting transition and a lower Jc.
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