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本文从实验以及理论研究两方面介绍了C60 与叠氮化合物的单加成反应。依照叠氮化合物的不同 ,C60 与叠氮化合物的单加成反应可分为烷基叠氮化物与C60 的反应、酰基叠氮化物与C60 的反应以及苯基叠氮化物与C60 的反应三类 ,而反应产物则为C60 亚氨基 [6,6]闭环衍生物和C60 亚氨基 [5 ,6]开环衍生物两类 ,不同类型的反应具有不同的反应机理 ,某些C60 亚氨基 [5 ,6]开环衍生物可以转化为C60亚氨基 [6,6]闭环衍生物。本文还介绍了碳纳米管与叠氮化合物的加成反应。
This article introduces the mono-addition reaction of C60 with azide from both experimental and theoretical aspects. In accordance with the different azide compounds, C60 and azide mono-addition reaction can be divided into alkyl azide and C60 reaction, acyl azide and C60 reaction and phenyl azide and C60 reaction three categories , While the reaction products are two kinds of ring-opening derivatives of C60 imino [6,6] and C60 imino [5,6]. Different types of reactions have different reaction mechanisms. Some of the C60 imino [5 , 6] Ring-opening derivatives can be converted to C 60 imino [6,6] closed-loop derivatives. This paper also introduced the addition reaction of carbon nanotubes with azide.