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《化学通报》1982年第5期所载“有机反应中瞬时碳正离子相对稳定性的判断法”一文,是作者蒋庆云同志对他三年前发表的一个观点的进一步阐述,并对陈家骏、刘福安同志所提问题的答复。蒋同志称之为“轨道成分及能量对比法”(以下简称“轨道法”)的新观点,我们觉得在该文论述中存在一些问题,有的是属于根本性的。为此,拟围绕该文中的主要问题提出我们的看法。
The article “Judgment of the Relative Stability of Instantaneous Carbon Cations in Organic Reactions” contained in the 5th Bulletin of Chemical Weapons Bulletin, 1982 was further elaborated by author Jiang Qingyun on a viewpoint he published three years ago. Reply of the questions raised by Comrade Fu An. Comrade Jiang described it as a new point of view in the Law of Orbital Components and Energy (hereinafter referred to as the “Orbital Law”). We think there are some problems in the argument of the article, and some are fundamental. To this end, we intend to put forward our views on the main issues in the article.