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利用高分辨电子显微技术(HREM)研究了钙稀土氟碳酸盐矿物晶体结构中的混层现象。在B_mS_n型规则混层矿物中发现了B_5S_4-3R和6R两种新多型,确定了它们的晶体结构类型、晶胞多数等,揭示出B_5S_4规则混层矿物不同多型体的超微结构特征,讨论了B_5S_4-6R多型晶体结构沿C方向的无序夹层和堆垛层错等晶体缺陷现象。
High-resolution electron microscopy (HREM) was used to investigate the mixed layer in the crystal structure of calcium-rich fluorocarbon minerals. Two new polymorphisms of B_5S_4-3R and 6R were found in the B_mS_n-type mixed bedded minerals, and their crystal structure types and unit cell numbers were determined. The ultrastructural features of different polytypes of B_5S_4 The phenomenon of crystal defects such as disordered interlayer and stacking faults along the C direction of B_5S_4-6R polycrystalline structure was discussed.