【摘 要】
：
CF3CF=CF2 is a potential source of atmospheric trifluoroacetic acid (CF3C(O)OH).The kinetics of the reaction of the simplest Criegee intermediate (CH2OO) with C
【机 构】
：
Key Laboratory of Chemical Lasers, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
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CF3CF=CF2 is a potential source of atmospheric trifluoroacetic acid (CF3C(O)OH).The kinetics of the reaction of the simplest Criegee intermediate (CH2OO) with CF3CF=CF2 was studied by using the OH laser-induced fluorescence method.At 10 torr,the rate coefficients were measured to be (1.45±0.14) × 10-13,(1.18±0.11) × 10-13,(1.11±0.08) × 10-13,and (1.04±0.08)×10-13 cm3·molecule-1·s-1 at 283,298,308 and 318 K,respectively.The activation energy of (-1.66±0.21) kcal/mol was derived from the Arrhenius equation.No obvious pressure dependence was observed.
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