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该文主要以色谱技术研究了负载型Ｎｉ（Ａｃ）＿２的热分解性能。结果表明，Ｎｉ（Ａｃ）＿２的分解过程取决于载体的性质。强酸性载体ＨＺＳＭ－５分子筛起催化分解作用，导致Ｎｉ（Ａｃ）＿２分解时在低温区出现ＣＨ＿４和ＣＯ＿２峰；ＭｇＯ与Ｎｉ（Ａｃ）＿２的配位作用致使Ｎｉ（Ａｃ）＿２有两个最佳分解温度，ＣＯ＿２，ＣＯ和Ｈ＿２相应地都出现两个峰；与ＭｇＯ和ＨＺＳＭ－５相比，ＳｉＯ＿２和γ－Ａ１＿２Ｏ＿３对Ｎｉ（ＡＣ）＿２热分解的影响不很明显。但ＳＯ＿２，γ－Ａ１＿２Ｏ＿３和ＨＺＳＭ－５有较强的甲烷化效应。
In this paper, the thermal decomposition of supported Ni (Ac) _2 was studied mainly by chromatographic techniques. The results show that the decomposition of Ni (Ac) _2 depends on the nature of the support. The catalytic decomposition of strongly acidic carrier HZSM-5 led to the formation of CH_4 and CO_2 peaks in the low temperature region during the decomposition of Ni (Ac) _2. The coordination between MgO and Ni (Ac) _2 resulted in two Ni There are two peaks corresponding to the optimum decomposition temperature, CO 2, CO and H 2, respectively. Compared with MgO and HZSM-5, the influence of SiO 2 and γ-Al 2 O 3 on the thermal decomposition of Ni (AC) 2 is not obvious. However, SO 2, γ-Al 2 O 3 and HZSM-5 have strong methanation effects.