【摘 要】
：
The title compound, {(H3O)4(NH4)4[Mo8O28]·2H2O}n 1, has been synthesized rature, and its crystal structure was determined by X-ray single-crystal analysis with
【机 构】
：
State Key Laboratory of Structural Chemistry
论文部分内容阅读
The title compound, {(H3O)4(NH4)4[Mo8O28]·2H2O}n 1, has been synthesized rature, and its crystal structure was determined by X-ray single-crystal analysis with the following crystallographic data: monoclinic system, space group P21/n, a = 9.5234(6), b = 11.3235(8),c = 14.8812(10) (A), β = 107.467(2)°, V= 1530.77(18) (A)3, Z= 4, F(000) = 1336,μ = 3.293 mm-1and Dc= 3.037 g/cm3. The final R = 0.0619 for 2691 observed reflections (I ＞ 2σ(I)). X-ray crystal structure analysis showed that the novel one-dimensional chain compound is built up by basic { Mo8O28 } units via singleμ2-O, and such chains are further linked into a three-dimensional network by hydrogen bonds.
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