Syntheses,Structures and Luminescent Property of Two Supramolecular Complexes Containing N-P-Acetami

• 作 者: 王新德 王永伟 尹卫平 王利亚 马录芳
• 机 构: Liming Research Institute of Chemical Industry,China Haohua (Grop) Co.,Department of Chemistry,Henan
• 出 处: 结构化学
• 发表日期: 2009年12期
• 关键词: glycine intermolecular supramolecular transitional bipyridine bonds complexes Li

Making use of N-P-acetamidobenzenesulfonyl-glycine acid (abbreviated as abglyH2),two transitional metal complexes [Zn(abglyH)(phen)2]ClO4·H2O (1) and Co(abglyH)2(bipy)2(H2O)2 (2) (phen = 1,10-phenanthroline,bipy = 4,4’-bipyridine) have been synthesized under mild conditions and characterized by IR,elemental analysis and X-ray diffraction analysis. Complex 1 is a monomeric compound which is further assembled by intermolecular hydrogen bonds and π-π interaction into a 2-D supramolecular network. Complex 2 is also a monomeric compound and further connected by intermolecular hydrogen bonds to form a 2-D supramolecular network. Fluorescent analysis shows that complex 1 has an emissive maximum at 364 nm in the solution state at room temperature.

Making use of NP-acetamidobenzenesulfonyl-glycine acid (abbreviated as abglyH2), two transitional metal complexes [Zn (abglyH) (phen) 2] ClO4 H2O and Co (abglyH) 2 (bipy) 2) (phen = 1,10-phenanthroline, bipy = 4,4’-bipyridine) have been synthesized under mild conditions and characterized by IR, elemental analysis and X-ray diffraction analysis. Complex 1 is a monomeric compound which is further assembled by intermolecular hydrogen bonds and π-π interactions into a 2-D supramolecular network. Complex 2 is also a monomeric compound and further connected by intermolecular hydrogen bonds to form a 2-D supramolecular network. Fluorescent analysis shows that complex 1 has an emissive maximum at 364 nm in the solution state at room temperature.