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本文研究了在碱性介质中,二过碘酸合银(Ⅲ)络离子引发丙烯腈自由基聚合反应,测得了各种条件对聚合反应速率的影响,给出了聚合反应速率和表观活化能,探讨了引发反应机理。
In this paper, we studied the radical polymerization of acrylonitrile induced by diperiodate silver (Ⅲ) complex ions in alkaline medium. The influence of various conditions on the polymerization rate was investigated. The polymerization rate and apparent activation Can, to explore the reaction mechanism.