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读了胡永寿同志《关于从质量作用定律引出化学平衡的问题》一文,感到其中心论点是正确的,即:对于合成氨这样的催化合成反应,其反应速度的表示式不能简单地套用质量作用定律,而必须考虑其反应机理。我是从事合成氨生产工艺工作的,也愿趁此机会,就胡同志所论问题,谈一些自己的看法。在合成氨的反应过程中,反应速度最慢的一步(如氨的化学吸附)被认为是一个基元反应,质量作用定律对它是完全适用的,即:这一反应的反应速度与各反
After reading Comrade Hu Yongshou’s article “On the Problem of Chemical Balance Derived from the Law of Quality and Effect,” I feel that its central argument is correct. That is, the reaction rate can not be simply applied to the law of mass action for catalytic synthesis such as ammonia synthesis , But must consider its reaction mechanism. I am engaged in the work of synthetic ammonia production process, is also willing to take this opportunity to talk about the issues discussed by Hutuo some of my own views. In the reaction of ammonia, the slowest reaction step (such as ammonia chemisorption) is considered as a elementary reaction, the law of mass action is completely applicable to it, namely: the reaction speed and the reaction