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1-氨基膦酸类的简便合成法DemirAS等[Tetra-hedronLett,1996;37:407]膦酸二乙酯与盐酸羟胺反应生成肟基膦液酯类,将其用NaBH4在MoO3或NiCl2存在下于甲醇中还原,得1-氨基膦酸酯。同样10例用MoO3时收率(6...
Simple synthesis of 1-aminophosphonates DemirAS et al [Tetra-hedron Lett, 1996; 37: 407] diethyl phosphonate and hydroxylamine hydrochloride react to form oximinoyl phosphonate esters, which are treated with NaBH4 in the presence of MoO3 or NiCl2 Reduction in methanol to give 1-amino phosphonate. The same 10 cases with MoO3 yield (6 ...