A novel and efficient synthesis of alkyl thiocyanates from alkyl halides in water using phase transf

• 作 者: Maryam Gorjizadeh Soheil Sayya
• 机 构: Department of Chemistry
• 出 处: 中国化学快报（英文版）
• 发表日期: 2004年期
• 关键词: Alkyl thiocyanate Alkyl halide l 4-Bis(triphenylphosphonium)-2-butene dichloride

1,4-Bis(triphenylphosphonium)-2-butene dichloride (BTPBDC) and 1,4-bis(triphenyl phosphonium)-2-butene dithiocyanate (BTPBDT) were prepared and used as phase-transfer catalysts. Alkyl halides were converted efficiently to the corresponding alkyl thiocyanates under mild reaction conditions in water. No evidence for the formation of isothiocy anates as by-product of the reaction was observed.