【摘 要】
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Morphology and dispersity are key factors for activating peroxymonosulfate (PMS).In this study,we designed a recyclable open-type NiCo2O4 hollow microsphere via a simple hydrothermal method with the assistance of an NH3 vesicle.The physical structure and
【机 构】
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College of Environmental Science and Engineering,Hebei University of Science and Technology,Shijiazh
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Morphology and dispersity are key factors for activating peroxymonosulfate (PMS).In this study,we designed a recyclable open-type NiCo2O4 hollow microsphere via a simple hydrothermal method with the assistance of an NH3 vesicle.The physical structure and chemical properties were characterized using techniques such as scanning electron microscope (SEM),transmission electron microscope (TEM),X-ray diffraction (XRD),N2 adsorption and X-ray photoelectron spectroscopy (XPS).The test results confirm that the inner and outer surfaces of open-type NiCo2O4 hollow-sphere can be efficiently utilized because of the hole on the surface of the catalyst,which can minimize the diffusion resistance of the reactants and products.Under optimized conditions,the total organic carbon (TOC) removal efficiency of rhodamine B(RhB) can reach up to 80％ in 40 min,which is almost 50％ shorter than the reported values.The reactive radicals were identified and the proposed reaction mechanism was well described.Moreover,the disturbances of HCO3-,NO3-,Cl-and H2PO4-were further investigated.As a result,HCO3-and NO3-suppressed the reaction while Cl-and H2PO4-had a double effect on reaction.
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