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本文提出了金属是其价电子在占据轨道和空轨道之间转移以及“自由”电子在晶间运动的混合体假设。运用此假设提出了(mp)~(1/2)/(n_en_0+n_er_a)的值应在一定的数域内,得到了1.006±0.103。还计算了m_p/(n_en_0+n_er_a)的三个周期的平均数值为1:1.155:1.322。这正好符合三个周期的电子动量比,即(n+(l(l+1))~(1/2))之比。经进一步假设电导与热导主要由“自由”机构起作用,得到了平均值分别为1.66±0.26和1.65±0.29的数域值。各个元素与这些平均值的偏离存在着规律性,表明两种结构对电导与热导都有贡献。不过在常温与熔点之间“自由”电子起着主要的作用。同时还推测了超导现象的可能机制。
In this paper, the hypothesis that a metal is a mixture of valence electrons traveling between occupied and empty orbitals and “free” electrons traveling through the intergranular is proposed. Using this hypothesis, it is proposed that the value of (mp) ~ (1/2) / (n_en_0 + n_er_a) should be within a certain number of domains, yielding 1.006 ± 0.103. The average of three cycles m_p / (n_en_0 + n_er_a) is also calculated as 1: 1.155: 1.322. This corresponds exactly to the three-cycle electron momentum ratio, that is, the ratio of (n + (l (l + 1)) ~ (1/2)). It is further assumed that the conductance and thermal conductance are mainly effected by the “free” mechanism, resulting in numerical values with mean values of 1.66 ± 0.26 and 1.65 ± 0.29, respectively. The deviation of each element from these averages is regular, indicating that both structures contribute to both conductance and thermal conductance. However, “free” electrons play a major role at room temperature and melting point. The possible mechanism of superconductivity is also speculated.