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By means of both the theory for pressure-induced shifts(PS)of energy spectra and the theory for shiftsof energy spectra due to electron-phonon interaction(EPI),at 300K,the‘pure electronic’contributions and the contri-butions from EPI to R_1 line,R_2 line,and U band of GGG:Cr~(3+)as well as their PS have been calculated,respectively.The total calculated results are in good agreement with all the experimental data.Their physical origins have beenexplained.It is found that the mixing-degree of|t(_2~2)(~3T_1)e~4T_2〉and|t_2~(32)E〉base-wavefunctions in the wavefunctions ofR_1 level of GGG:Cr~(3+)is considerable under normal pressure,and the mixing-degree rapidly decreases with increasingpressure.The change of the mixing-degree with pressure plays a key role for PS of R_1 line or R_2 line.At 300K,boththe temperature-independent contribution to R_1 line(or R_2 line or U band)from EPI and the temperature-dependentone are important.The remarkable difference between pressure-dependent behaviors of PS of R_1 lines of GGG:Cr~(3+)andGSGG:Cr~(3+)results from the differences of their microscopic properties.The features of emission spectra of GGG:Cr~(3+)at various pressures have satisfactorily been explained.
By means of both the theory for pressure-induced shifts (PS) of energy spectra and the theory for shifts of energy spectra due to electron-phonon interaction (EPI), at 300K, the’pure electronic’contributions and the contributions from EPI to R_1 line, R_2 line, and U band of GGG: Cr ~ (3+) as well as their PS have been calculated, respectively. The total calculated results are in good agreement with all the experimental data. Their physical origins have beenexplained. It is found that the mixing-degree of | t (_2 ~ 2) (~ 3T_1) e~4T_2> and | t_2 ~ (32) E> base-wavefunctions in the wavefunctions ofR_1 level of GGG: Cr ~ (3+ is considerably under normal pressure, and the mixing-degree rapidly decreases with increasing pressure. The change of the mixing-degree with pressure plays a key role for PS of R_1 line or R_2 line. At 300K, both the temperature-independent contribution to R_1 line or R_2 line or U band) from EPI and the temperature-dependentone are important. remarkable difference between pressure-dependent beh aviors of PS of R_1 lines of GGG: Cr ~ (3+) and GSGG: Cr ~ (3+) results from the differences of their microscopic properties. These features of emission spectra of GGG: Cr ~ (3+) at various kinds of satisfactorily been explained.