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本文报道借~1H NMR方法研究了四种新的N-双取代二苯并氮杂冠醚化合物(1~4)和对甲苯重氮氟硼酸盐在CDCl_3-CD_3CN中的配合作用,并计算了以上配合物的稳定常数,简扼讨论了取代基团的改变对配合作用的某些影响.
In this paper, the coordination between four novel N-disubstituted dibenzoazacrown compounds (1 ~ 4) and p-toluidofluoroborates in CDCl 3 -CD_3CN was studied by ~ 1H NMR and calculated The stability constants of the above complexes were briefly discussed and some of the effects of the substitution of the substituent groups on the coordination were discussed briefly.