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合成并表征了一个全新的双核铜(Ⅱ)穴合物,并首次利用脉冲辐解法来研究双核铜(Ⅱ)穴合物(SOD模型物)与反应动力学,结果表明该铜(Ⅱ)穴合物的催化速率常数可达1.89×107,铜(Ⅱ)穴合物催化歧化为一级反应。
A new double dinuclear copper (Ⅱ) cryptate was synthesized and characterized. The pulsed radiocarbon method was used for the first time to study the kinetics of dinuclear copper (Ⅱ) cryptate (SOD) and its reaction kinetics. The catalytic rate constant of the compound reached 1.89 × 107, and the copper (Ⅱ) cryptate catalyzed disproportionation as the first order reaction.