【摘 要】
:
Functional group transformations are central to organic synthesis.Traditionally,the functionalities used in such transformations are highly active organic group
【机 构】
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College of Chemistry and Green Chemistry Center,Peking University,
【出 处】
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National Science Review
论文部分内容阅读
Functional group transformations are central to organic synthesis.Traditionally,the functionalities used in such transformations are highly active organic groups such as halogens,ester groups and hydroxyl groups.Carbon–hydrogen bonds are ubiquitous structural motifs in organic compounds,but they are not considered to be functionalgroups because(1)in general,the bond dissociation energy of a C–H bond is high,and therefore,such bonds
Functional group transformations are central to organic synthesis. Traditionally, the functionalities used in such transformations are highly active organic groups such as halogens, ester groups and hydroxyl groups. Carbon-hydrogen bonds are ubiquitous structural motifs in organic compounds, but they are not considered to be functionalgroups (1) in general, the bond dissociation energy of a C-H bond is high, and therefore, such bonds
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