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丁二醇二丙烯酸酯、丙烯酸甲酯、丙烯酸β-氯乙酯或丙烯酸ω-氯己酯进行三元共聚,合成了两类4种带ω-氯侧基的交联型聚丙烯酸酯.它们以乙硫醇硫醚化,再与氯亚铂酸钾反应,得到4种交联型聚丙烯酸酯负载的硫铂络合物.这些络合物对癸烯-1、十二烯-1、苯基烯丙醚、苯乙烯与三乙氧基硅烷的硅氢加成反应具有良好的催化活性.讨论了温度、催化剂用量对催化性能的影响及催化剂的重复使用情况.
Butylene glycol diacrylate, methyl acrylate, β-chloroethyl acrylate or ω-chlorohexyl acrylate were used to make two types of cross-linked polyacrylates with ω-chloro side groups. Thioethane etherification, and then reacted with Potassium Potassium Platinum Platinum to obtain four kinds of cross-linked polyacrylate-supported thioplatin complexes.These complexes were successfully synthesized by the reaction of decene-1, dodecene-1, The hydrosilylation reaction of phenyl allyl ether, styrene and triethoxysilane has good catalytic activity, and the influence of temperature and amount of catalyst on the catalytic performance and the repeated use of catalyst are discussed.