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在室温下测量了KTiOPO_4单晶的偏振喇曼散射谱,应用90°散射及背散射得到了各模的峰位值,其中B_1(LO)模、B_2(LO)模的喇曼谱测量尚未见报道过。根据LO-TO劈裂的实验结果,计算出该晶体极化模的有效电荷、振子强度及沿对称轴方向的静态介电常数。
The polarization Raman scattering spectra of KTiOPO_4 single crystal were measured at room temperature. The peak position values of each mode were obtained by 90 ° scattering and backscattering. The Raman spectra of B_1 (LO) mode and B_2 (LO) mode have not been observed yet Reported before. According to the experimental results of LO-TO cleavage, the effective charge, oscillator strength and static permittivity along the symmetry axis of the crystal were calculated.