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One new chiral metal-organic coordination polymer,[Cd_2(dpb)(H_2hfipbb)_2]_n,was obtained under hydrothermal conditions of 1,3-di(pyridineyl)benzene(dpb) and 4,4'-(hexafluoroisopropylidene)bis(benzoic acid)(H_2hfipbb). The title compound reveals a thr