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在弱碱性介质中,CTMAB微乳液存在下,5-(3-苯甲酸偶氮)-8-氨基喹啉(CPAQ)与钯(Ⅱ)生成3:1蓝色络合物,λmax=625nm,ε=9.40×104。钯的含量在0-20μg/25mL内符合比尔定律。方法用于钯催化剂中钯的测定,结果满意。
In a mild alkaline medium, a 3: 1 blue complex of 5- (3-benzoic acid azo) -8-aminoquinoline (CPAQ) and palladium (II) is formed in the presence of CTMAB microemulsion with λmax = 625 nm , Ε = 9.40 × 104. Beer’s law is obeyed at 0-20 μg / 25 mL. The method was applied to the determination of palladium in palladium catalyst with satisfactory results.