论文部分内容阅读
本文进一步考察了电化学氧化黄县油页岩过程。利用DSC、IR等分析技术研究了反应前后油页岩有机质性质的变化情况。初步认为电解氧化优先发生在油页岩有机质的芳环结构单元上,导致油页岩有机质三维网络结构的破裂,形成大量羧酸。反应过程中的氧化剂主要为阳极产生的活性氧基团而不是分子氧。
This paper further investigated the electrochemical oxidation of oil shale Huangxian process. The changes of organic matter properties of oil shale before and after the reaction were studied by DSC, IR and other analytical techniques. It is preliminarily believed that electrolytic oxidation preferentially occurs on the aromatic ring structural units of the organic matter of oil shale, leading to the rupture of the three-dimensional network structure of the organic matter of the oil shale and the formation of a large amount of carboxylic acids. The oxidant during the reaction is mainly the active oxygen group produced by the anode rather than the molecular oxygen.