Changes of crystal structure and hydrogen storage performances for multiphase La0.7Mg0.3Ni3 alloy up

• 作 者: Yi-Ming Li Han-Wei Zhang Yang-Huan Zhang Zhuo-Cheng Liu Hui-Ping Ren
• 机 构: School of Materials Science and Engineering,Shanghai University,Shanghai 200072,China;Analytical and
• 出 处: 稀有金属（英文版）
• 发表日期: 2017年2期
• 关键词: RE-Mg-Ni hydrogen storage alloys Gassolid cycling Partial amorphization Capacity

In order to examine the effects of structure stability on the degradation behaviors of multiphase La0.7Mg0.3Ni3 alloy,changes of the crystal structure and hydrogen storage properties after gas-solid cycling were investigated in detail.The structural analysis identifies that (La,Mg)Ni3 (PuNi3-type) phase transforms to amorphous,i.e.,hydrogen-induced amorphization(HIA) occurs whereas LaNi5 (CaCu5-type),(La,Mg)2Ni7 (Ce2Ni7-type),and (La,Mg)5Ni19 (Pr5Co19-type) phases still keep crystalline upon hydriding/dehydriding cycling.Partial amorphization remarkably affects both the gas-solid and electrochemical storage performances.The plateau of PCT curves becomes narrow and steep with cycling.Moreover,the maximum electrochemical capacity decreases notably after gas-solid hydrogenation repeats.The electrochemical capacity reduction could be ascribed to both drop of the maximum storage capacity and the slope of plateau induced by partial amorphization.For direct electrochemical cycling,it is suggested that the capacity decay is mainly attributed to HIA in the initial stage.