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原子转移自由基聚合反应 ( ATRP)是一种新的活性自由基聚合方法 ,自 1995年提出后 ,引起高分子合成化学及工业界的关注。本文详细介绍了 ATRP在端功能基聚合物、大分子单体、嵌段共聚物、接枝共聚物、星形聚合物、梯度共聚物、超支化聚合物等聚合物分子设计中的应用
Atom transfer radical polymerization (ATRP) is a new active radical polymerization method, which has been proposed since 1995 and has attracted the attention of polymer synthesis chemistry and industry. This paper introduces the application of ATRP in the design of polymer molecules such as terminal functional polymer, macromonomer, block copolymer, graft copolymer, star polymer, gradient copolymer and hyperbranched polymer