Kinetics of Hydrothermal Reactions of Minerals in Near-critical and Supercritical Water

来源 :Acta Geologica Sinica(English Edition) | 被引量 : 0次 | 上传用户:liuxing20090113
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This work presents new experimental results on the kinetics of mineral dissolution in near-critical and supercritical water in a temperature range (T) from 25 to 400℃ and a constant pressure of 23 MPa. Kinetic experiments were carried out by using a flow reactor (packed bed reactor) of an open system. The dissolution rates of albite and magnetite were measured under these experimental conditions. Na, Al and Si release rates for albite dissolution in water were measured as a function of the temperature and flow velocity in the reaction system. The maximum release rates of Na, AI and Si of albite dissolution in the hydrothermal flow systems under different flow velocities were always obtained at 300℃, that is to say, the maximum albite dissolution rates in the flow systems, regardless of different flow rates, were repeatedly measured at 300℃. Results indicate a wide fluctuation in albite dissolution rates occurring close to the critical point of water. The dissolution rates increased when the temperatu This work presents new experimental results on the kinetics of mineral dissolution in near-critical and supercritical water in a temperature range (T) from 25 to 400 ° C and a constant pressure of 23 MPa. Kinetic experiments were carried out by using a flow reactor ( packed bed reactor) of an open system. The dissolution rates of albite and magnetite were measured under these experimental conditions. Na, Al and Si release rates for albite dissolution in water were measured as a function of the temperature and flow velocity in the reaction system . The maximum release rates of Na, AI and Si of albite dissolution in the hydrothermal flow systems under different flow velocities were always obtained at 300 ° C, that is to say, the maximum albite dissolution rates in the flow systems, regardless of different flow rates Results indicate a large fluctuation in albite dissolution rates occurring close to the critical point of water. The dissolution rates increas ed when the temperatu
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