论文部分内容阅读
本文应用化合物同系线性规律公式,来表达同族元素及其化合物各种性能中递变关系的规律。 利用同系因子(1/α)~(2/n)作为代表同族原子大体结构效应的因素,用方程式 P=a+b(1/α)(2/n),(α≥2)联系了各主族元素及其化合物的约二十种性能(P),包括元素的电离势、电子亲和力和各种电负性、原子及离子半径,以及化合物中的键能、键极性、电导和Born—Haber循环中所包括的各种能量。 讨论了同族元素性能中线性递变规律性不如化合物同系线性规律的原因。
In this paper, the law of homology linear relationship of compounds is used to express the regularity of the graded relationship between the elements and their compounds. Using the same factor (1 / α) ~ (2 / n) as the factor that represents the general structure effect of the atoms of the same family, About twenty main properties (P) of the main group elements and their compounds, including the ionization potentials, electron affinity and various electronegativities of the elements, atomic and ionic radii, as well as bond energies, bond polarity, conductance, and Born -Haber cycle includes a variety of energy. The reason for the linear regularity of the same elements in the same family is not as good as the homology regularity of the compounds.