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The title complex [Cu(L1)(L2)(H2O)]·H2O(1,HL1 = N-(imino(pyridin-2-yl)me-thyl)picolinamidine),HL2 = salicylic acid) has been obtained by volatilization method with L1 prepared from 2,4,6-tripyridyl-1,3,5-triazine in situ.1 was fully characterized by single-crystal X-ray diffraction,elemental analysis and FT-IR.This complex exhibits a three-dimensional frame-work constructed through hydrogen bonding and C-H···π stacking interactions.The cyclic voltametric behavior of complex 1 was also investigated.1 belongs to the monoclinic system,space group P21/c with a = 15.112(5),b = 7.115(2),c = 19.899(6) ,β = 112.32°,V = 1979.4(11) 3,Mr = 460.94,Dc = 1.540 g/cm3,F(000) = 948,μ = 1.146 mm-1,Z = 4,the final R = 0.0612 and wR = 0.1813 for 2510 observed reflections with I > 2σ(I).
The title complex [Cu (L1) (L2) (H2O)] H2O (HL1 = N- (imino (pyridin- 2-yl) me- thyl) picolinamidine, HL2 = salicylic acid) has been obtained by volatilization method with L1 prepared from 2,4,6-tripyridyl-1,3,5-triazine in situ.1 was fully characterized by single-crystal X-ray diffraction, elemental analysis and FT-IR.This complex exhibits a three- frame-work constructed through hydrogen bonding and CH · π stacking interactions. The cyclic voltametric behavior of complex 1 was also investigated.1 belongs to the monoclinic system, space group P21 / c with a = 15.112 (5), b = 7.115 (2), c = 19.899 (6) β, β = 112.32 °, V = 1979.4 (11) 3, Mr = 460.94, Dc = 1.540 g / cm3, F (000) = 948, μ = 1.146 mm-1 , Z = 4, the final R = 0.0612 and wR = 0.1813 for 2510 observed reflections with I> 2σ (I).