Balancing the Activity and Selectivity of Propane Oxidative Dehydrogenation on NiOOH(001)and(010)

• 作 者: Lisheng Li Hua Wang Jinyu Han
• 机 构: CollaborativeInnovationCentreofChemicalScienceandEngineering,DepartmentofChemistryandBiochemistry
• 出 处: 天津大学学报:英文版
• 发表日期: 2020年5期
• 关键词: Density functional theory Oxidative dehydrogenation PROPANE Nickel oxide hydroxi
• 基金项目: the National Natural Science Foundation of China(Nos.21873067 and 21576204).

Propane oxidative dehydrogenation(ODH)is an energy-efficient approach to produce propylene.However,ODH suff ers from low propylene selectivity due to a relatively higher activation barrier for propylene formation compared with that for further oxidation.I