Combination of Lindqvist-type Tungstovanadates and Transition Metal Clusters under Hydrothermal Con

• 作 者: LI Jie LIU Yun MA Peng-Tao
• 机 构: BasicExperimentTeachingCenter,InstituteofMolecularandCrystalEngineering
• 出 处: 结构化学
• 发表日期: 2013年2期
• 关键词: 过渡金属簇合物 水热条件 多金属氧酸盐 单晶X-射线衍射 杂多化合物 聚阴离子 铜离子 杂多阴离子 polyoxometalate hydrothermal
• 基金项目: This work was supported by the Foundation of Education Department of Henan Province

<正>Two novel organic-inorganic heteropolyoxometalate compounds [{Cu(1,10- phen)OH}_2]_2[V_2W_4O_19]·6H_2O (1) and [Co(1,10-phen)_3]_2[V_2W_4O_(19)]·5H_2O (2) (1,10-phen = 1,10- phenanthroline) were hydrothermally synthesized and characteri