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通过(μ-BrMgS)(μ-n-C_4H_9S)Fe_2(CO)_6与CH_2=共轭加成及中间物的醇解反应先制得(μ-n-C_4H_9S)(μ-)Fe_2(CO)_6,然后进一步将它同PPh_3反应制得标题配合物,该簇合物晶体属C2/c空间群,α=30.892(4),b=12.454(2),c=25.725(4);β=91.46(1)°,Z=8;Dc=1.284 g/cm~3;R=0.060,其簇核由2个铁原子和2个硫原子构成蝶式结构,2个三苯膦配体处于铁—铁变键反位,2个桥硫原子上的取代基团均以e键与硫原子相连。
(Μ-n-C_4H_9S) (μ-) Fe_2 (CO) _6 (μ-n-C_4H_9S) was synthesized by the conjugate addition reaction of μ- , And then further reacted with PPh_3 to obtain the title complex which belongs to the C2 / c space group with a = 30.892 (4), b = 12.454 (2), c = 25.725 (1) °, Z = 8; Dc = 1.284 g / cm ~ 3; R = 0.060. The cluster nucleus is composed of two iron atoms and two sulfur atoms. The two triphenylphosphine ligands are in iron- Iron iron bond transposition, the two bridge sulfur atom substitution groups are connected with the sulfur atom by e bond.