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C-H amination by iron-imido/nitrene species has attracted increasing research interest in recent years because of its potential use in economical and environmentally benign syntheses of amino compounds.With the aim of providing a comprehensive overview of this field,which is of interest to both the synthetic organic and inorganic communities,this paper reviews the status quo of C-H amination chemistry by iron-imido/nitrene intermediates,as well as by well-defined iron-imido/nitrene compounds,with special emphasis on their structure/reactivity correlations.Achievements,problems,and perspectives in this growing field are discussed.
CH amination by iron-imido / nitrene species has absorbed increasing research interest in recent years because of its potential use in economical and environmentally benign syntheses of amino compounds .With the aim of providing a comprehensive overview of this field, which is of interest to both the synthetic organic and inorganic communities, this paper reviews the status quo of CH amination chemistry by iron-imido / nitrene intermediates, as well as by well-defined iron-imido / nitrene compounds, with special emphasis on their structure / reactivity correlations.Achievements , problems, and perspectives in this growing field are discussed.