Synthesis,Structure and Properties of a New Silver Nitrate Complex

• 作 者: 崔毅鑫 杨文斌 谢兴昆 吴小园 卢灿忠
• 机 构: College of Chemistry,Fuzhou University,State Key Laboratory of Structural Chemistry,Fujian Institute
• 出 处: 结构化学
• 发表日期: 2015年11期
• 关键词: pyrid ambient triclinic transformed silver supramolecular chair zigzag Silver bi

A new metal-organic coordination polymer,[Ag(L)(NO3)]n(1,L=β-amino-β-(pyrid-2-yl)acrylonitrile),has been synthesized by solvent method at ambient temperature and characterized through single-crystal diffraction,Fourier transformed infrared spectrum(FTIR),elemental analysis,thermogravimetry analysis(TGA) and fluorescent measurements.1 crystallizes in the triclinic system,space group P1 with a=7.3600(3),b=8.5095(17),c=9.2936(14) ?,α=66.65(6),β=70.56(7),γ=71.59(6)o,V=492.4(4) ?3,μ=2.043 mm-1,Dc=2.104 Mg/m3,Z=2,Mr=312.01,F(000)=302,the final R=0.0347 and w R=0.0987 for 3924 observed reflections with I > 2σ(I).

A new metal-organic coordination polymer, [Ag (L) (NO3)] n (1, L = β-amino-β- (pyrid-2-yl) acrylonitrile) has been synthesized by solvent method at ambient temperature and characterized (17) crystallographic in the triclinic system, space group P1 with a = 7.3600 (3), b = 8.5095 , c = 9.2936 (14)?,? = 66.65 (6),? = 70.56 (7),? = 71.59 (6) o, V = 492.4 (4)? 3,? = 2.043 mm-1 and Dc = 2.104 Mg / m3, Z = 2, Mr = 312.01, F (000) = 302, the final R = 0.0347 and w R = 0.0987 for 3924 observed reflections with I> 2σ (I).