1,2-环氧环己烷和1,2-二氯乙烷二元体系汽液平衡数据的测定与关联(英文)

来源 :Chinese Journal of Chemical Engineering | 被引量 : 0次 | 上传用户:MAOMAO1002333141
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Vapor-liquid equilibrium data (T, x, y) of binary system 1,2-epoxycyclohexane + 1,2-dichloroethane were determined experimentally by using a modified ROSE-Williams equilibrium vaporization system at 101.33 kPa. The results show that this binary system does not have azeotropic point. The vapor-liquid equilibrium data are in thermodynamic consistency. The binary interaction parameters in the Wilson equation are presented with the correlation of vapor-liquid equilibrium data. The measurements of liquid phase composition and bubble point temperature are well represented by the Wilson equation. Values of vapor molecular fractions and activity coefficients from the Wilson equation are presented. This work provides important engineering data for the separation of 1,2-dichloroethane and 1,2-epoxycyclohexane . Vapor-liquid equilibrium data (T, x, y) of binary system 1,2-epoxycyclohexane + 1,2-dichloroethane were determined experimentally by using a modified ROSE-Williams equilibrium vaporization system at 101.33 kPa. The results show that this binary system The vapor-liquid equilibrium data are in thermodynamic consistency. The vapor-liquid equilibrium data are in thermodynamic consistency. The measurements of liquid phase composition and bubble point temperature are well represented by the Wilson equation. Values ​​of vapor molecular fractions and activity coefficients from the Wilson equation are presented. This work provides important engineering data for the separation of 1,2-dichloroethane and 1,2-epoxycyclohexane.
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