Highly mechanical and high-temperature properties of Cu-Cu joints using citrate-coated nanosized Ag

来源 :自然科学进展·国际材料(英文) | 被引量 : 0次 | 上传用户:red0035
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Today,a growing number of third-generation semiconductor-based power devices are used in products that can continuously operate at high temperatures for extended periods of time.Hence,traditional tin-lead and lead-free solders are no longer suitable for modern electronic packaging.A common method is to apply Ag paste for bare Cu-Cu joints under an inert or reductive atmosphere.In this study,the citrate-coated nanosized Ag paste was utilized to generate robust bare Cu-Cu joints under atmospheric conditions.The average size of citrate-coated Ag particles was approximately 4.76 nm after being cleaned by deionized water and acetone.The effects of process parameters,such as cleaning,joining temperature,holding time,and joining pressure,on the mechanical prop-erties of the bare Cu-Cu joints were thoroughly investigated.Increasing washing and joining temperatures resulted in a shear strength increase of up to 28.2 MPa at a joining temperature of 260 ℃ after seven washes.In addition,a holding time of 30 min and a joining pressure of 1 MPa were selected as optimal process conditions for the application of citrate-coated nanosized Ag paste onto bare Cu-Cu joints.The newly developed Cu-Cu joints showed excellent thermal stability at 150 ℃ using the citrate-coated nanosized Ag paste.After long-term aging,the joints exhibited stability at 250 ℃ for 144 h,indicating a good high-temperature reliability for three-dimensional integrated circuits (3D ICs) fabricated under atmospheric conditions.
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