【摘 要】
：
合成了Eu(TTA) 3 ·Phen和Eu0 .8Y0 .2 (TTA) 3 ·Phen固体配合物微晶粉末及其掺杂的SiO2 凝胶样品 .在30 0～ 80 0nm测定并解释了其光声光谱 .在配体吸收处 ,Eu0 .8Y0 .2 (TTA
【机 构】
：
南京大学声学研究所,中国科学技术大学化学系,南京大学声学研究所 近代声学国家重点实验室,南京210093,合肥230026,近代声学国家重点实验室,南京210093
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合成了Eu(TTA) 3 ·Phen和Eu0 .8Y0 .2 (TTA) 3 ·Phen固体配合物微晶粉末及其掺杂的SiO2 凝胶样品 .在30 0～ 80 0nm测定并解释了其光声光谱 .在配体吸收处 ,Eu0 .8Y0 .2 (TTA) 3 ·Phen的光声强度低于Eu(TTA) 3 ·Phen的光声强度 ;而对于配合物掺杂的凝胶样品 ,则情况相反 .Y3 + 的引入改变了配合物的弛豫过程 ,且配合物在粉末和凝胶状态下 ,弛豫历程不尽相同 .结合荧光光谱研究了标题化合物的发光特性 ,并建立了能量传递模型 .
Eu (TTA) 3 · Phen and Eu0 .8Y0.2 (TTA) 3 · Phen solid complex microcrystalline powders and their doped SiO2 gel samples were synthesized and their photoacoustic properties were measured and explained at 30 0 ~ 80 0 nm The photoacoustic intensity of Eu0.8Y0.2 (TTA) 3 · Phen was lower than the photoacoustic intensity of Eu (TTA) 3 · Phen at the absorption of the ligand, whereas for the gel-doped samples, On the contrary, the introduction of Y3 + changed the relaxation process of the complexes, and the complexes showed different relaxation processes in powder and gel state.The luminescence properties of the title compounds were studied by fluorescence spectroscopy, and the energy transfer model .
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