[｛Zn(3-SBA)(2,2'-bipy)(H_2O)_2｝·H_2O]n的合成和晶体结构研究

• 作 者: 李文戈 王作为 蔡亚 许正江 李一志 郑和根
• 机 构: 南京大学配位化学研究所配位化学国家重点实验室,南京大学配位化学研究所配位化学国家重点实验室,江苏技术师范学院贵金属深加工技术及应用省重点实验室,南京大学配位化学研究所配位化学国家重点实验室,南京大学配
• 出 处: 无机化学学报
• 发表日期: 2005年12期
• 关键词: 锌配合物 H_2O]n SBA Zn bipy H_2O 晶体结构 荧光性质 磺酸 苯甲酸

A novel coordination ploymer [{Zn(3-SBA)(2,2′-bipy)(H2O)2}·H2O]n was synthesized by the hydrothermal reaction of 3-Na2SBA, ZnSO4·7H2O and 2,2′-bipy. The structure was characterized by elemental analysis, IR and single crystal X-ray diffraction. The title coordination ploymer crystallized in monoclinic with space group P21, a=0.803 42(18) nm, b=1.501 8(3) nm, c=0.821 13(19) nm, β=109.350(4)°. The coordination polymer has an infinite chain structure and its luminescent property has also been studied. CCDC: 282746.

A novel coordination ploymer [{Zn (3-SBA) (2,2’-bipy) (H2O) 2} · H2O] n was synthesized by the hydrothermal reaction of 3-Na2SBA, ZnSO4 · 7H2O and 2,2’-bipy The structure was characterized by elemental analysis, IR and single crystal X-ray diffraction. The title coordination ploymer crystallized in monoclinic with space group P21, a = 0.803 42 (18) nm, b = 1.501 8 (3) nm, c = 0.821 13 (19) nm, β = 109.350 (4) °. The coordination polymer has an infinite chain structure and its luminescent property has also been studied. CCDC: 282746.