【摘 要】
：
The bicyclic product containing a chromene skeleton and a propargylamine skeleton(C_(22)H_(22)N_2O_2) was synthesized from the double sites of terminal alkyne,
【机 构】
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Anhui Provincial Laboratory of Optoelectronic and Magnetism Functional Materials,Anqing Normal Unive
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The bicyclic product containing a chromene skeleton and a propargylamine skeleton(C_(22)H_(22)N_2O_2) was synthesized from the double sites of terminal alkyne, piperazine derivative and formaldehyde via one-pot procedure. Its structure was characterized by ~1H NMR, ~(13)C NMR, IR and H RMS, and further confirmed by single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n with a = 12.6571(14), b = 11.3249(12), c = 12.6571(14) ?, β = 105.22°,V = 1750.6(3) ?~3, Z = 4, R = 0.0568 and w R = 0.1444. The fluorescence of the product was discussed.
The bicyclic product containing a chromene skeleton and a propargylamine skeleton (C_ (22) H_ (22) N_2O_2) was synthesized from the double sites of terminal alkyne, piperazine derivative and formaldehyde via one-pot procedure. , 13 C NMR, IR and H RMS, and further confirmed by single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group P21 / n with a = 12.6571 (14), b = 11.3249 ), c = 12.6571 (14)?,? = 105.22 °, V = 1750.6 (3)? 3, Z = 4, R = 0.0568 and wR = 0.1444.
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