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采用 TG-DTG技术研究了稀土铕 ( Eu3+ )与对硝基苯甲酸 ( p-NBA)及 2 ,2’-联吡啶 ( dipy)配合物在静态空气中的热分解过程 ,运用 Achar法和 Coats-Redfern法 ,推断出该配合物第 2～ 4步热分解的非等温动力学方程 .同时给出了相应的动力学补偿效应的表达式 .
The thermal decomposition process of europium (Eu3 +) and p-NBA and 2,2’-dipyridyl complexes in static air was studied by TG-DTG technique. Achar method and Coats -Redfern method was used to infer the non-isothermal kinetic equations of the thermal decomposition of the complexes from the second to the fourth step, and the expressions of the corresponding kinetic compensation effects were given.