【摘 要】
：
Electrolytic fixation of CO2 was investigated by electrocarboxylation of organic halides (RX), and four esters (I, II, III, IV) were obtained in moderate yields
【机 构】
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College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China,Colle
【出 处】
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Chinese Journal of Chemistry
论文部分内容阅读
Electrolytic fixation of CO2 was investigated by electrocarboxylation of organic halides (RX), and four esters (I, II, III, IV) were obtained in moderate yields. Electrochemical reduction esterifications of RX in the presence of CO2 were carried out on nanocrystalline TiO2-Pt electrode. The electrochemical behavior of RX in the presence of CO2 was investigated by the technique of cyclic voltammetry, and the probable reaction mechanism was proposed.
Electrolytic fixation of CO2 was investigated by electrocarboxylation of organic halides (RX), and four esters (I, II, III, IV) were obtained in a moderate yield. Electrochemical reduction esterifications of RX in the presence of CO2 were carried out on nanocrystalline TiO2- The electrochemical behavior of RX in the presence of CO2 was investigated by the technique of cyclic voltammetry, and the probable reaction mechanism was proposed.
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