Crystal Structure and Solution Behavior of a Novel Enantiopure Helical Coordination Polymer Based on

• 作 者: JIN Ri-zhe BIAN Zheng HE Ya-bi
• 机 构: StateKeyLaboratoryofPolymerPhysicsandChemistry,GraduateSchoolofChineseAcademyofSciences
• 出 处: 高等学校化学研究：英文版
• 发表日期: 2010年6期
• 关键词: 配位聚合物 晶体结构 光学纯 螺旋 配体 联萘 行为 基础 Helical structure Binapthyl Silver Chiral ligand S
• 基金项目: Supported by the National Natural Science Foundation of China（No.20502024）

An enantiopure helical coordination polymer AgPF6·(R)-3 as crystalline solid was synthesized by the self-assembly of chiral binaphthyl-based ligand(R)-6,6'-di[6-(2,2'-bipyridyl)]-2,2'-diethoxyl-1,1'-binaphthalene [(R)-3] and Ag+ ion.T