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用循环伏安法、计时库仑法研究了Ｂｒ－在不同电极上，以及不同浓度与不同ｐＨ值时的电氧化性质．测定了Ｂｒ－在１ｍｏｌ／ＬＨ２ＳＯ４介质中的扩散系数Ｄ和标准电极反应速度常数ｋ°．实验结果表明Ｂｒ－在Ｐｔ上的反应速度常数要比石墨电极上大一个数量级．根据不同实验条件的循环伏安图，提出了Ｂｒ－电氧化的可能机理．
Cyclic voltammetry and chronometric coulometry were used to investigate the electrooxidation properties of Br-on different electrodes and at different concentrations and pH values. The diffusion coefficient D of Br- in 1 mol / LH 2 SO 4 medium and the standard electrode reaction rate constant k ° were measured. The experimental results show that the reaction rate constant of Br- on Pt is one order of magnitude larger than that of graphite electrode. According to the cyclic voltammograms of different experimental conditions, the possible mechanism of Br-electrooxidation was proposed.