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We investigate the thermal expansion property of the Tb2Fe14Cr3 compound by means of x-ray diffraction.The result shows that the Tb2Fe14Cr3 compound has a hexagonal Th2Ni17-type structure.Negative thermal expansion is found in the Tb2Fe14Cr3 compound from 296 to 493K by x-ray dilatometry.The coefficient of the average thermal expansion is (a)=-2.82×10-5 K-1.In the temperature range 493-692K,the coefficient of the average thermal expansion is (a)=1.59×10-5 K-1.The physical mechanism of thermal expansion anomaly of the Tb2Fe14Cr3 compound is discussed according to the temperature dependence of magnetization measured by a superconducting quantum interference device.