Effect of CeO2 and Al2O3 on the activity of Pd/Co3O4/cordierite catalyst in the three-way catalysis

• 作 者: Sergiy O. Soloviev Pavlo I. Kyriienko Nataliia O. Popovych
• 机 构: L. V. Pisarzhevsk Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kyiv 030
• 出 处: 环境科学学报（英文版）
• 发表日期: 2012年7期
• 关键词: metal-oxide catalysts structured catalysts effect of CeO2 and Al2O3 CO NO CnHm c

The present article studies the effect of CeO2 and Al2O3 on the activity of Pd/Co3O4/cordierite catalyst in conversion of NO,CO,CnHm.The catalysts were characterized by temperature programmed reduction with hydrogen,X-ray diffraction,X-ray photoelectron spectroscopy and transmission electron microscopy.It is shown that the effect of CeO2 on the properties of Pd/Co3O4/cordierite catalyst depends on preparation method.The catalyst obtained by co-deposition of cerium and cobalt oxides has higher activity in CO oxidation (CO + O2 and CO + NO) and total hexane oxidation (C6H14 + O2).Such phenomenon is probably caused by more than stoichiometric amount of formed oxygen vacancies,an increase in both mobility of surface oxygen and dispersity of components in the catalytic composition.It is demonstrated that CeO2 addition promotes the SO2 resistance of Pd/Co3O4/cordierite.The second support decreases the activity of Pd/Co3O4/cordierite catalyst in the reactions of CO and C6H14 with oxygen because of CoAl2O4 formation.