Hierarchically porous Fe_2O_3 /CuO composite monoliths:Synthesis and characterization

来源 :Journal of Natural Gas Chemistry | 被引量 : 0次 | 上传用户:Toowell_Star
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In this paper,hierarchically porous Fe2O3 /CuO composite monoliths were first successfully synthesized by a mild method using silica monoliths as templates.The structure of composite monoliths was characterized by X-ray diffraction,scanning electron microscopy,nitrogen adsorption-desorption.The results indicated that the molar ratio of Fe to Cu had a great influence on the crystal phase of Fe2O3,pore size and the structure of the macroporous wall.The Fe2O3 /CuO composite monoliths consist of hierarchically macroporous and mesoporous structure,while the sample with the Fe/Cu molar ratio of 2:1 possesses tighter wall structure than other samples.It is expected that asprepared Fe2O3/CuO composite monoliths have potential applications in several fields as catalysts,catalyst supports,chemical sensors and high-performance liquid chromatography (HPLC). In this paper, hierarchically porous Fe2O3 / CuO composite monoliths were first synthesized synthesized by a mild method using silica monoliths as templates. The structure of composite monoliths was characterized by X-ray diffraction, scanning electron microscopy, nitrogen adsorption-desorption.The results indicated that the molar ratio of Fe to Cu had a great influence on the crystal phase of Fe2O3, pore size and the structure of the macroporous wall. Fe2O3 / CuO composite monoliths consist of hierarchically macroporous and mesoporous structures, while the sample with the Fe / Cu molar ratio of 2: 1 possesses tighter wall structure than other samples. It is expected that asprepared Fe2O3 / CuO composite monoliths have potential applications in several fields as catalysts, catalyst supports, chemical sensors and high-performance liquid chromatography (HPLC).
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