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A new star-shaped donor-acceptor molecule has been synthesized for application as the donor material in solution-processed bulk-heterojunction organic solar cells (OSCs). The molecule consists of a triphenylamine (TPA) unit as the core and a donor unit with three arms containing benzo[1,2,5]thiadiazole (BT) acceptor units and 5,5’’-dihexyl-2,2′:3′,2″-terthiophene (tTh) end groups. The molecule, denoted S(TPA-BT-tTh), exhibits a broad absorption band in the wavelength range 300-650 nm and high hole mobility of 1.1×10 -4 cm2 V -1 s 1 . An OSC device based on S(TPA-BT-tTh) as donor and [6,6]-phenyl C71 -butyric acid methyl ester (PC 70 BM) as the acceptor (1:3, w/w) exhibited a power conversion efficiency of 2.28% with a short circuit current density of 6.39 mA/cm2 under illumination of AM.1.5, 100 mW/cm2 .
A new star-shaped donor-acceptor molecule has been synthesized for application as the donor material in solution-processed bulk-heterojunction organic solar cells (OSCs). The molecule consists of a triphenylamine (TPA) unit as the core and a donor unit with Three arms containing benzo [1,2,5] thiadiazole (BT) acceptor units and 5,5 ’’ - dihexyl-2,2 ’: 3’, 2 "-terthiophene (tTh) TPA-BT-tTh), exhibits a broad absorption band in the wavelength range of 300-650 nm and high hole mobility of 1.1 × 10 -4 cm2 V -1 s 1. An OSC device based on S (TPA-BT-tTh) as donor and [6,6] -phenyl C71 -butyric acid methyl ester (PC 70 BM) as the acceptor (1: 3, w / w) exhibited a power conversion efficiency of 2.28% with a short circuit current density of 6.39 mA / cm2 under illumination of AM.1.5, 100 mW / cm2.