The effects of ultrasound frequency and power on the activation energy in Si-KOH reaction system

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:BENLAOQIAN
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The activation energy is the minimum amount of energy required to initiate a reaction.It is one of the important indexes for appraising a reartion.The chemical reaction rate is closely related to the value of activation energy,and reducing activation energy is propitious to promoting a chemical reaction.In the present paper,the relationship between the activation energy in Si-KOH reaction system and the ultrasound frequency and power has been discussed for the first time.The range of ultrasound frequency and power is 40-100 kHz(interval by 20 kHz) and 10-50 W(interval by 10 W),respectively.The experimental data indicate that the activation energy decreases with the increasing ultrasound power.Comparing with the activation energy without ultrasound irradiation,the results in our paper indicate that ultrasound irradiation could reduce the activation energy in Si-KOH reaction system and increase the reaction rate. The activation energy is the minimum amount of energy required to perform a reaction. It is one of the important indexes for appraising a reartion. The chemical reaction rate is closely related to the value of activation energy, and reducing activation energy is propitious to promoting a chemical reaction. In the present paper, the relationship between the activation energy in Si-KOH reaction system and the ultrasound frequency and power has been discussed for the first time. The range of ultrasound frequency and power is 40-100 kHz (interval by 20 kHz) and 10-50 W (interval by 10 W), respectively. the experimental data indicate that the activation energy decreases with the increasing ultrasound power. Comparing with the activation energy without ultrasound irradiation, the results in our paper paper that ultrasound irradiation could reduce the activation energy in Si-KOH reaction system and increase the reaction rate.
其他文献
探讨米非司酮(Mifepristone)配伍米索前列醇终止15~26周妊娠的引产效果。观察组70例,用米非司酮配伍米索前列醇引产。对照组68例,用利凡诺引产,结果:米非司酮配伍米索前列醇组
南水北调中线工程是一项特大型水利工程,它的建成将大大改善供水区生态环境和投资环境,推动我国中部地区的经济发展。南水北调中线工程属于明渠开挖,挖方量远远大于回填量,存
本文从图书馆学历史说起,分析了当前图情学遇到危机的原因,以及对学科名称提出争论的几家观点,初步探讨了信息管理学科群各学科的关系及如何摆正它们的位置,最后提出集成化是
A convenient and efficient protocol for the synthesis of unnatural N-glycosyl a-amino acids was developed.Condensation of 1,3,4,6-tetra-O-actyl-β-D-glucosamine
今年以来,国内企业继续登记炔草酯不同单剂产品。其中,安徽省利辛县百胜农药化工有限责任公司获批登记了24%乳油产品,安徽省四达农药化工有限公司登记了15%微乳剂产品,杭州宇
对二维光子晶体的电磁波理论及周期性介质中的Bloch波解做了详细的推导,给出了光子晶体中的禁带存在的理论依据,同时以三角晶格的二维光子晶体为例,采用平面波展开方法对果糖
醛在氨水作用下与碘(1.06 eq)室温反应30 min后,直接与二硫代磷酸二乙酯(1 eq)于90℃反应2 h,得相应的硫代伯酰胺,18例收率76%~93%。苯甲醛或苯乙醛芳环上带供电子基收率高于
The conventional collector for diaspore mineral is oleic acid,which is highly insoluble and must be used in high dosage in bauxite flotation,that is the great d
世界著名经济学家本·巴恩斯认为,发展知识经济,政府的指导、规划、激励、调控是必要条件,为做到这一点,就需要政府有比传统市场经济更为强大的宏观调控能力。这一点在1993年2月美国总
剖宫产术是产科常见的手术,术中出血又是其常见的并发症,控制术中出血的方法有很多,而宫腔填塞纱布条是一种较古老的方法,近年来我院将此法重新应用于控制剖宫产术中出血共2