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The initiation mechanism of organic hydroperoxide and amine system has been investigatedsystematically in this paper. It has been confirmed from the IR spectra that organic hydro-peroxide could form hydrogen-bonded complex with amine. The reactive intermediate of theamine and its effect on initiating polymerization have been determined by using ESR techni-que, and further proved by the results of polymer end group analysis and graft copolymeri-zation of vinly monomer onto the amino-containig polymer. Finally, water, as one of the finalproducts of ROOH-amine reaction has been detected through chromatographic analysis, fromwhich the conversion reaction of the reactive intermediate is verified.
The initiation mechanism of organic hydroperoxide and amine system has been systematically in this paper. It has been confirmed from the IR spectra that organic hydro-peroxide could form hydrogen-bonded complex with amine. The reactive intermediate of theamine and its effect on initiating polymerization have has determined by using ESR techni-que, and further proved by the results of polymer end group analysis and graft copolymeri-zation of vinly monomer onto the amino-containig polymer. Finally, water, as one of the final products of ROOH-amine reaction has been detected through chromatographic analysis, fromwhich the conversion reaction of the reactive intermediate is verified.