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在水热条件下合成了金属-有机配位聚合物:[Co(BDC)(phen)-(H2O)]n.3nH2O(BDC=1,4-benzenedicarboxylate,phen=1,10-phenanthroline),并通过元素分析,IR光谱,TG和单晶X-射线衍射对其进行了表征。结构表明该化合物属于三斜晶系:P-1(2)空间群组;晶胞参数a=9.795(5),b=10.752(5),c=11.271(5),α=75.903(5)°,β=65.306(5)°,γ=86.042(5)°,V=1045.3(9)3,C20H22CoN2O8,Mr=477.13,Dc=1.908g.cm-3,μ(MoKα)=1.637mm-1,Z=2,R1=0.1586,wR2=0.3906。该化合物表现出Z字连状结构。
The metal-organic coordination polymer [Co (BDC) (phen) - (H2O)] n.3nH2O (BDC = 1,4-benzenedicarboxylate, phen = 1,10-phenanthroline) was synthesized under hydrothermal conditions. It was characterized by elemental analysis, IR spectroscopy, TG and single crystal X-ray diffraction. The structure shows that the compound belongs to triclinic system: space group P-1 (2); cell parameters a = 9.795 (5), b = 10.752 (5), c = 11.271 (5), α = 75.903 °, β = 65.306 (5) °, γ = 86.042 (5) °, V = 1045.3 (9) 3, C20H22CoN2O8, Mr = 477.13, Dc = 1.908g.cm- 3, μ (MoKα) = 1.637mm-1 , Z = 2, R1 = 0.1586, wR2 = 0.3906. The compound shows a zig-zag structure.